O ) and the subsequent synthesis and characterization of related complexes SAMUEL
نویسنده
چکیده
A hydrated tris-( cis-vinyl-1,2 –bis(diphenylphosphineoxide))manganese(II)perchlorate, [Mn(cisPh2P(O)CH=CHP(O)Ph2)3](ClO4)2.(H2O) crystal structure has been determined and characterized. The complex was serendipitously discovered while attempting to obtain crystal of its bis-ligand analogue. In its structure the the monoclinic crystal is unique in coordination chemistry in that it contains a rare strained seven-member chelate ring system. Six or five coordinate complex are common but not seven-membered ring systems. The complex was then synthesized which shows to be a white air stable complex.
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تاریخ انتشار 2011